Thursday, January 27, 2011
Chapter 13 Muddiest Point
My muddiest point from chapter 13 is interpreting infared spectrums. I understand no observable data can be retrieved from the fingerpoint region. My main misunderstanding is how carbonyl groups are located on the spectrum. I know that each absorption depends on the particular types but do not understand how rings and double bonds are identified. I found in chapter 21 that aldehydes and ketones give a strong peak at 1700 due to the C-O double bond. I also found that the sp3 hybridized C-H bond of an aldehyde shows one or two peaks at 2700-2830. These exact positions of the carbonyl absorptions provide additional information about a compound. For example, most aldehydes have a C-O double bond peak around 1730 and ketones peak around 1715. The carbonyl absorption of cyclic ketones shifts to a higher wavenumber as the size of the ring decreases and the ring strain increases. Weaker bonds absorb at a lower frequency on the spectrum. After reading this section of chapter 21, I understand more about how to interpret carbonyl groups on infared spectrums.
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All of the different peaks and where things are located on the spectrum is a lot to take in and understand. I think it will all come with practice. You seem to be thorough about the info you found about the different peaks and where they occur. Good work on the blog
ReplyDelete-The High School Chemist
At first, I was a little confused with this same concept, but after reading the text, I began to figure it out. You did a good job describing the different regions on the spectrum and their wavelenths. Your blog is very pretty too! Good job! :)
ReplyDeleteAfter reading this and both of the comments, I have to agree with everyone, this is a tough topic. When I first read it in the book, I didn't understand it either, but after searching on the internet, I found this website:http://academics.keene.edu/rblatchly/OrgoCommon/hand/Spectroscopy/iruv/IRCorrelation.html
ReplyDeleteThis website really made things clear for me, it shows steps and gives examples as well.To be honest, I thought this website was a lot more helpful then the book was, because it goes step by step and gives examples and shows the graphic version of each. Overall, I think you did a good job!
-Alexia